Final answer:
The diagnosis for the neonate presenting with bilious vomiting and irritability, abdominal distention, and high-pitched bowel sounds is volvulus.
Step-by-step explanation:
The diagnosis for the 2-day-old neonate presenting with bilious vomiting and irritability, abdominal distention, and high-pitched bowel sounds, as well as a dilated sigmoid colon with a column of barium resembling a 'coffee bean' on barium enema radiograph, is volvulus. Volvulus is a condition in which the intestine twists on itself, causing obstruction and compromising blood supply. This can result in symptoms like vomiting, abdominal distention, and abnormal bowel sounds.