Final answer:
In PCl3, phosphorus has 1 lone pair, 4 electron domains, and all atoms follow the octet rule. Phosphorus has no formal charge, and the Lewis structure shows 26 valence electrons, not 28.
Step-by-step explanation:
The structures of phosphorus trichloride (PCl3) can be analyzed using Lewis structures which show the arrangement of valence electrons. The Lewis structure of PCl3 is determined by following these steps:
- Count the total number of valence electrons. Phosphorus has 5 valence electrons and each chlorine has 7 valence electrons, giving a total of 26 (5 from phosphorus + 3*7 from chlorine).
- Arrange electrons to fulfill the octet rule. Each chlorine atom needs 8 electrons to complete its octet, which it achieves by forming a single bond with phosphorus (sharing one pair of electrons with phosphorus) and having three lone pairs.
- After forming three P-Cl bonds, phosphorus has 3 electron domains from bonds and one lone pair, which is the fourth electron domain.
Based on this analysis:
- Phosphorus does have 1 lone pair.
- All atoms follow the octet rule.
- Phosphorus does not have a formal charge since it shares one electron with each of the three chlorines and has one lone pair, resulting in its octet being complete without the need for a formal charge.
- The structure shows 26 valence electrons, not 28.
- Phosphorus has 4 electron domains, 3 from bonds and 1 from the lone pair.