Final answer:
NH₃ is the limiting reactant in the reaction, with approximately 2.58 moles available option (a). Calculations based on stoichiometry show that NH₃ is consumed completely while O₂ is in excess. Therefore, 119 g of NO₂ is produced.
Step-by-step explanation:
To determine the limiting reactant in the reaction of NH₃ with O₂, we must calculate the moles of each reactant and then compare the stoichiometric ratio dictated by the balanced equation.
The balanced chemical equation is: 4NH₃(g) + 7O₂(g) → 4NO₂(g) + 6H₂O(g).
To find the moles of NH₃ and O₂, we use their given masses and molar masses:
- Moles of NH₃ = 43.9 g / 17.03 g/mol = approximately 2.58 moles.
- Moles of O₂ = 258 g / 32.0 g/mol = approximately 8.06 moles.
Now, we compare the moles of each reactant to the stoichiometric coefficients in the balanced equation. For every 4 moles of NH₃, 7 moles of O₂ are required. Thus:
- Required moles of O₂ for 2.58 moles of NH₃ = (2.58 moles NH₃) × (7 moles O₂ / 4 moles NH₃) ≈ 4.51 moles of O₂.
Since we have 8.06 moles of O₂ available, which is more than the required 4.51 moles, NH₃ is the limiting reactant.
Now, we can calculate the amount of NO₂ produced from the limiting reactant:
- Moles of NO₂ produced = (2.58 moles NH₃) × (4 moles NO₂ / 4 moles NH₃) = 2.58 moles of NO₂.
- Mass of NO₂ produced = 2.58 moles × 46.01 g/mol = 118.75 g, which we can round to 119 g.
NH₃ is the limiting reactant; 119 g NO₂ is produced.