Final answer:
The acid/base combinations that can be used to prepare a buffer solution are HNO₂ and NaNO₂, and HCN and KCN, and KH₂PO₄ and K₂HPO₄.
Step-by-step explanation:
A buffer solution is a solution that is resistant to changes in pH when small amounts of acid or base are added. In order to prepare a buffer solution, you need a weak acid and its conjugate base or a weak base and its conjugate acid.
From the given options, the acid/base combinations that can be used to prepare a buffer solution are:
- HNO₂ (weak acid) and NaNO₂ (conjugate base)
- HNO₂ (weak acid) and NaNO₃ (not correct because NaNO₃ is the salt of a strong acid and strong base)
- HCN (weak acid) and KCN (conjugate base)
- KH₂PO₄ (weak acid) and K₂HPO₄ (conjugate base)