Final answer:
Brachiopods have two layers in their shell; the periostracum as the first layer secreted by the mantle, and a second layer of calcium carbonate for articulate brachiopods or calcium phosphate for inarticulate brachiopods.
Step-by-step explanation:
The brachiopod shell has two layers and while they share some superficial resemblance to bivalves, their shell structure is quite unique. The first layer, known as the periostracum, is secreted by the mantel tissue. This outer organic layer provides initial protection and may deter predators or prevent fouling. The internal layers constitute the main shell and vary between two types of brachiopods: articulate and inarticulate brachiopods.
In articulate brachiopods, the second layer contains hard mineralized materials, typically calcium carbonate in two forms - calcite and aragonite. This composition contributes to the rigidity and protective capacity of the shell. In contrast, inarticulate brachiopods have a second layer that is mostly constituted of calcium phosphate along with some organic material, which makes it different in both texture and composition from that of their articulate counterparts.