Final answer:
In chromatography using a polar adsorbent like silica gel, less polar compounds elute first because they interact less strongly with the adsorbent compared to more polar compounds, which elute later.
Step-by-step explanation:
With a polar adsorbent such as silica gel, the compound that elutes first is less polar than the compound that elutes last. In chromatography, a less polar substance tends to have weaker interactions with the polar adsorbent and thus moves through the system more quickly than more polar compounds, which establish stronger interactions and elute later.