Final answer:
To preserve a urine sample for reliable pH testing, it should be tested within 1 hour of collection to prevent changes in pH caused by chemical reactions, such as urea converting to ammonia.
Step-by-step explanation:
To maintain the reliability of a urine pH sample, it should be tested within 1 hour of collection. Urine pH can vary significantly due to the buffering action of bicarbonate, dihydrogen phosphate ion, or ammonia in the urine, and because urea can convert to ammonia over time, changing the pH. Quick testing helps prevent such changes from occurring, ensuring a more accurate reading. It's important to also note that if the urine cannot be tested within an hour, refrigeration can help preserve its integrity until testing.