Final answer:
The electron transport chain in cellular respiration utilizes redox reactions to create an electrochemical gradient of hydrogen ions across the inner membrane of the mitochondria. This gradient drives ATP synthesis through the ATP synthase enzyme.
Step-by-step explanation:
The electron transport chain in cellular respiration uses the energy from redox reactions to pump hydrogen ions (protons) across the inner membrane of the mitochondria. This creates a concentration gradient and an electrical gradient, collectively called an electrochemical gradient. The accumulation of hydrogen ions on one side of the membrane results in a higher concentration outside the membrane. The flow of hydrogen ions back into the matrix through the ATP synthase enzyme drives ATP synthesis.