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Give the three classifications of dienes (according to proximity) and their definitions.

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Final answer:

Dienes are classified based on the proximity of their double bonds: cumulated dienes (adjacent double bonds), conjugated dienes (alternate double and single bonds allowing electron delocalization), and isolated dienes (double bonds separated by two or more single bonds).

Step-by-step explanation:

The three classifications of dienes according to proximity are cumulated dienes, conjugated dienes, and isolated dienes.

  • Cumulated dienes have two double bonds that share a common carbon atom, as seen in allenes.
  • Conjugated dienes contain two double bonds separated by a single sigma bond, allowing for delocalization of electrons; an example is 1,3-butadiene.
  • Isolated dienes feature two double bonds separated by two or more single bonds, which prevents delocalization between the double bonds; an example is 1,5-hexadiene.
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