Final answer:
Starch's branching structure allows for easy enzymatic access, aiding in rapid digestion.
Step-by-step explanation:
The structure of a starch molecule relates to its function in the following way: a) Starch's branching structure allows for easy enzymatic access, aiding in rapid digestion. Starch is composed of two polymers: amylose (linear) and amylopectin (branched). The branching structure of amylopectin provides more surface area for enzymes to break down the molecule into glucose, allowing for faster digestion and energy release.