Final answer:
The percent of water by mass in magnesium carbonate pentahydrate (MgCO3 · 5H2O) is 51.7%. The correct dehydration equation is MgCO3 · 5H2O → MgCO3 + 5H2O.
Step-by-step explanation:
To determine the percent of water by mass in magnesium carbonate pentahydrate (MgCO3 · 5H2O), you must calculate the total mass of water (5 moles of H2O) and divide it by the molar mass of the entire compound.
- Molar mass of water (H2O) = 18.015 g/mol
- Molar mass of magnesium carbonate (MgCO3) = 84.31 g/mol
- Molar mass of hydrate = 84.31 g/mol (MgCO3) + 5 × 18.015 g/mol (H2O) = 174.385 g/mol
- Mass of water in hydrate = 5 × 18.015 g/mol = 90.075 g
- Percent of water = (90.075 g / 174.385 g/mol) × 100% = 51.7%
The correct dehydration equation for magnesium carbonate pentahydrate is:
MgCO3 · 5H2O → MgCO3 + 5H2O