Final answer:
Atracurium is the drug most likely to cause muscle pain post-operatively.
Step-by-step explanation:
The drug most likely to cause muscle pain post-operatively is Atracurium.
Atracurium is a neuromuscular blocking agent that is commonly used during anesthesia to induce muscle relaxation. However, it can also cause muscle pain and stiffness as a side effect.
Suxamethonium, Propofol, and Ketamine are not typically associated with muscle pain post-operatively. Suxamethonium is a depolarizing neuromuscular blocking agent that can cause muscle fasciculations, but not prolonged muscle pain. Propofol is a general anesthetic that does not have muscle pain as a side effect. Ketamine is a dissociative anesthetic that may cause muscle rigidity, but not muscle pain.