Final answer:
Polarization in dielectric materials occurs when electric dipoles align with an external electric field, resulting in net surface charges. The induced surface charges create an additional electrical field that opposes the external field within the slab.
Step-by-step explanation:
The concept of polarization in dielectric materials refers to the alignment of electric dipoles within the material when it is placed in an electric field. When a nonconducting slab with a volume charge density undergoes polarization, the electric dipoles within it align with the external electric field. This alignment, however, only produces net charges at the surfaces of the slab, while the dielectric as a whole remains neutral. The induced surface charges create an additional electrical field that opposes the external field within the slab.