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Write the IUPAC name of the compound Pt(en)₂​Cl₂​. Draw the structures of geometrical isomers. Which of them is optically active and optically inactive?

User Piraces
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Final answer:

The IUPAC name of the compound Pt(en)₂​Cl₂​ is diaminedichloridoplatinum(II). The compound exhibits geometric isomerism with cis and trans configurations. Both isomers are optically inactive.

Step-by-step explanation:

The IUPAC name of the compound Pt(en)₂​Cl₂​ is diaminedichloridoplatinum(II).

To draw the structures of geometrical isomers, we need to determine the possible arrangements of the ligands around the central platinum atom. In this case, the two ligands are the bidentate ligand ethylenediamine (en) and the chloride ion (Cl⁻).

The compound Pt(en)₂​Cl₂​ exhibits geometric isomerism due to the presence of two different ligands, which can arrange themselves in cis or trans configurations. The cis isomer has the same ligands on the same side of the square planar complex, while the trans isomer has the ligands on opposite sides.

The cis isomer of Pt(en)₂​Cl₂​ can be represented as [Pt(en)₂​Cl₂​]cis, and the trans isomer as [Pt(en)₂​Cl₂​]trans.

In terms of optical activity, both cis and trans isomers of Pt(en)₂​Cl₂​ are optically inactive because they lack a chiral center and do not exhibit the ability to rotate plane-polarized light.

User Fidsah
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