Final answer:
The correct statement in relation to the triple points of CO₂ and H₂O is that at the pressure where water is at its triple point, CO₂ can only exist as a solid or gas. Option number d is correct.
Step-by-step explanation:
The student's question asks about the triple point of carbon dioxide (CO₂) compared to that of water (H₂O). Based on the provided information, the correct statement is that at the pressure where water is at its triple point, carbon dioxide can only exist as a solid or a gas, as per option D.
The carbon dioxide triple point occurs at a higher pressure and lower temperature compared to water’s triple point. Hence, carbon dioxide requires a pressure of approximately 5.11 atm to reach its triple point where it can exist as a solid, liquid, and gas in equilibrium. In contrast, water only requires 0.00600 atm of pressure to reach its triple point.