Final answer:
NAD+ accepts electrons to become NADH in glycolysis, which can be used to produce ATP in later stages of cellular respiration.
Step-by-step explanation:
The role of NAD+/NADH in glycolysis is that NAD+ accepts electrons to become NADH. During the second phase of glycolysis, glyceraldehyde-3-phosphate dehydrogenase converts glyceraldehyde-3-phosphate into 1,3-bisphosphoglycerate, releasing an electron that is picked up by NAD+ to create NADH. The NADH molecules produced in glycolysis carry high-energy electrons that can be used to produce ATP in later stages of cellular respiration.