Final answer:
The species [Cu(NH3)4(H2O)2]2+ corresponds to a Cu(II) ion complex, and the species [Zn(NH3)4(H2O)2]2+ corresponds to a Zn(II) ion complex.
Step-by-step explanation:
The species [Cu(NH3)4(H2O)2]2+ is a complex ion that forms when ammonia (NH3) is added to an aqueous solution containing Cu(II) ions. Similarly, the formation of the species [Zn(NH3)4(H2O)2]2+ signifies the formation of a complex ion involving Zn(II) ions. Therefore, the correct answer to the question is A) Cu(II) ion, Zn(II) ion.