Final answer:
The 2-L bottle of water lost more heat because it had a greater mass, and in calorimetry, the amount of heat loss is dependent on mass, specific heat, and temperature change.
Step-by-step explanation:
The second student's answer is correct; the 2-L bottle of water lost more heat because it had a greater mass of water to cool down. In terms of heat transfer, the amount of heat lost or gained by a substance is directly proportional to the mass of the substance, the change in temperature, and the specific heat capacity. Therefore, the larger mass of the 2-L bottle would account for more heat loss. The first student's answer is incorrect because while the starting and ending temperatures are the same for both bottles, heat loss is also a function of mass, not just temperature change. The third student's error is assuming the rate of cooling correlates with the total heat loss, which is not necessarily true. The rate of cooling can be faster for smaller quantities due to the ratio of surface area to volume, but total heat lost is still dependent on mass. The fourth student's skepticism overlooks that the final temperature is given as the 'temperature of the refrigerator,' suggesting a standard reference point.