Final answer:
The masses of a 0.583 molar solution of iron(III) nitrate needed to obtain specific moles of substance are 34.3 g for 0.0200 moles of iron(III) nitrate, 85.8 g for 0.0500 moles of Fe³⁺ ions and 1.716 g for 0.00300 moles of nitrate ions.
Step-by-step explanation:
To determine the mass of a 0.583 molar solution of iron(III) nitrate needed to obtain various amounts of iron(III) nitrate and its ions, we'll use molarity and stoichiometry.
a) To obtain 0.0200 moles of iron(III) nitrate:
Molarity (M) = moles of solute / volume of solution (L)
0.583 M = 0.0200 moles / V
V = 0.0200 moles / 0.583 M
V = 0.0343 L
Now, to find the mass, we need the density of the solution, but since it's not provided, we'll assume the density is similar to water (1 g/mL) for the purpose of this demonstration:
Mass = Volume × Density = 0.0343 L × 1000 mL/L × 1 g/mL = 34.3 g
b) The mole ratio of iron(III) to iron(III) nitrate is 1:1, therefore 0.0500 moles of Fe³⁺ ions is also 0.0500 moles of iron(III) nitrate:
0.583 M = 0.0500 moles / V
V = 0.0500 moles / 0.583 M
V = 0.0858 L
Mass = 0.0858 L × 1000 mL/L × 1 g/mL = 85.8 g
c) Each mole of iron(III) nitrate gives 3 moles of nitrate ions, so 0.00300 moles of nitrate ions equals 0.00100 moles of iron(III) nitrate:
0.583 M = 0.00100 moles / V
V = 0.00100 moles / 0.583 M
V = 0.001716 L
Mass = 0.001716 L × 1000 mL/L × 1 g/mL = 1.716 g