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For propanoic acid (HC3H5O2, Ka = 1.3 x 10-5) Determine the percent dissociation of a 0.29 M solution.

1 Answer

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The percent dissociation of a 0.29 M solution is

0.210%.

What is buffer solution?

Given that

ka = 1.3 x 10⁻⁵

Initial concentration of HC₃H₅O₂ = 0.29

ka = [H⁺]x[C₃H₅O⁻]/[HC₃H₅O₂]

Let denote the concentration of HC₃H₅O₂ that dissociates to be y.

Therefore,

1.3 x 10⁻⁵ = y * y/0.29 - y

0.000013 = y²/0.29 - y

0.000013(0.29 - y) = y²

0.00000377 - 0.000013y = y²

y² + 0.000013y - 0.00000377 = 0

Let solve

y = (+-b√(b² - 4ac))/2a

where

a = 1

b = 0.000013

c = - 0.00000377

Substitute into y = (+-b√(b² - 4ac))/2a

y = 0.000013 +-√(0.000013)² + 4*1*0.00000377))/2*1

y = 0.000013 +-√(0.0000151)/2

= (0.000013 +- 0.00123)/2

Since concentration cannot be negative

y = (0.000013 + 0.00123)/2

= 0.00609

The concentration of the acide that dissociates is

0.00609

The percentage = (0.00609 * 100)/0.29

= 0.210%.

User Marwan Alqadi
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