Final answer:
0.275 mol of carbon monoxide escaped from the container. This was calculated using the molar volume ratio (Avogadro's Law) which states that at constant temperature and pressure, equal volumes of gases contain the same number of moles, given the initial and final volumes of the gas.
Step-by-step explanation:
The student's question revolves around the principles of gas laws, particularly Avogadro's Law, which states that at constant temperature and pressure, equal volumes of gases contain the same number of moles. Given that carbon monoxide (CO) is a toxic gas, when a container with 14.0L volume containing 0.625mol of CO is found later to have a volume of 8.01L under the same conditions, we're asked to calculate how many moles of CO have escaped.
To determine the number of moles that escaped, we can compare the initial and final conditions using the molar volume ratio:
- Initial Volume/Initial Moles = Final Volume/Final Moles
Therefore, solving for Final Moles (moles remaining in the container) we get:
Final Moles = (Initial Moles × Final Volume) / Initial Volume
Final Moles = (0.625 mol × 8.01 L) / 14.0 L = 0.35 mol
Now subtract the moles remaining from the initial moles to find moles escaped:
Moles Escaped = Initial Moles - Final Moles = 0.625 mol - 0.35 mol = 0.275 mol
So, 0.275 mol of carbon monoxide must have escaped from the container.