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It is observed that air is a homogeneous mixture of 20% by volume O₂(g) and 80% by volume N₂(g). With the help of given information estimate the volume of air which is required for complete combustion of 360 g C₅H₁₂(g) at 1 atm and 273K

A. 896L%
B. 2240L%
C. 4480L
D. Data insufficient

User Saurav
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Final answer:

To completely combust 360 g of C₅H₁₂, we calculate the moles of C₅H₁₂ and moles of O₂ needed. At STP, 896 L of O₂ is required for combustion, and since air is 20% O₂, we need a total of 4480 L of air. The correct option is C.

Step-by-step explanation:

The question concerns how much volume of air is required for the complete combustion of 360 g of pentane (C₅H₁₂) at 1 atm and 273 K. First, the balanced chemical equation for the combustion of pentane must be determined:

C₅H₁₂ + 8 O₂ → 5 CO₂ + 6 H₂O

One mole of C₅H₁₂ requires 8 moles of O₂ for complete combustion. Using the molar mass of C₅H₁₂, which is 72.2 g/mol, we can calculate the moles of C₅H₁₂:

360 g C₅H₁₂ × (1 mole/72.2 g) = 5 moles C₅H₁₂

Since one mole of pentane needs 8 moles of O₂, 5 moles of pentane will need:

5 moles C₅H₁₂ × 8 moles O₂/mole C₅H₁₂ = 40 moles O₂

At STP (Standard Temperature and Pressure), one mole of any gas occupies 22.4 liters, so:

40 moles O₂ × 22.4 L/mole = 896 L O₂

Considering that air is 20% O₂ by volume, the total volume of air needed is:

896 L O₂ ÷ 0.20 = 4480 L air

The correct answer for the given problem is 4480 L of air.

User K M Rejowan Ahmmed
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