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Which of the following molecules have octahedral geometry?

A. SF6
B. CBr4
C. XeF4
D. BrF3

User Dominictus
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Final answer:

BrF3 does not exhibit octahedral geometry; it features a T-shaped structure. Octahedral geometry requires six regions of electron density, such as in the molecule XeOF4, which has a square pyramidal structure. BF3, however, is trigonal planar, not octahedral.

Step-by-step explanation:

The molecule BrF3 does not have octahedral geometry. Instead, BrF3 adopts a T-shaped molecular structure, which stems from a trigonal bipyramidal electron geometry but with two positions occupied by lone pairs leading to a molecular geometry that has three nuclei determining its shape.

For a molecule to exhibit an octahedral geometry, there should be six regions of electron density surrounding the central atom. An example would be XeOF4, which not only has an octahedral electron-group geometry but also has a square pyramidal molecular structure due to its combination of four single bonds, a double bond, and a lone pair on the central atom. On the other hand, BF3 possesses a trigonal planar geometry, which is defined by three atoms arranged around the central atom in a flat triangle.

The determination of molecular geometry involves understanding the spatial arrangement of bonds and lone pairs around the central atom, utilizing principles like VSEPR theory to predict the three-dimensional shape of the molecule.

User Teodor Scorpan
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