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A and B react stoichiometrically to form P. If 0.01-M A and 10-M B are mixed, it is found that the log of the concentration of A vs. time is a straight line. (a) What is the order of the reaction with respect to A? (b) Write a one-line mechanism that is consistent with the kinetics and stoichiometry. (c) According to your mechanism, what is the order of the reaction with respect to B?

User Acrilige
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Final answer:

The reaction is first-order with respect to both A and B, resulting in an overall reaction order of 2. A one-line mechanism compatible with the kinetics and stoichiometry would be a bimolecular reaction, A + B → P. The orders of the reaction are consistent with the law of mass action.

Step-by-step explanation:

The student has described a reaction where A and B react to form P, and the log of the concentration of A vs. time plots as a straight line. This indicates that the reaction is first-order with respect to A, meaning the rate at which A reacts is directly proportional to its concentration at any given time. If the concentration of A were to double, for instance, the rate of the reaction would also double.

A one-line mechanism consistent with the observed kinetics and stoichiometry would be a simple bimolecular reaction, such as A + B → P, where each collision between A and B has a chance to lead to product formation. Given that the reaction is first-order with respect to A, and knowing that the reaction rate ratio is proportional to the product of the concentrations of A and B, it is consistent to deduce that the reaction is also first-order with respect to B. Therefore, the overall reaction order is 2, which is the sum of the orders with respect to both A and B.

The concentration of B does not alter the kinetics assuming B is in vast excess (10 M compared to 0.01 M for A), which means B's concentration effectively remains constant over the course of the reaction, and thus, the reaction appears to be first-order overall—this is often termed a pseudo-first-order reaction contextually.

User Iacks
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