Final answer:
The term 'brachio-' refers to the arm and is used in anatomical terms such as brachial artery, brachial plexus, and brachial vein, specifically describing structures related to the upper arm.
Step-by-step explanation:
The term that is of or relating to the arm is brachio- (option 6).
This prefix is used in various medical and anatomical terms, such as brachial artery, which is a major blood vessel of the (upper) arm; the brachial plexus, which is a network of nerves that sends signals from the spinal cord to the shoulder, arm, and hand; and the brachial vein, which helps to facilitate blood return from the arm to the heart.
The term 'brachium' is specifically reserved for the upper arm, making option 6 the most appropriate answer.