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What does it mean when a diatomic molecule is homonuclear?

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Final answer:

A homonuclear diatomic molecule consists of two atoms of the same element, and it is described using molecular orbitals. The stability and polarity of the molecule depend on the filling of the molecular orbitals and the difference in electronegativity.

Step-by-step explanation:

A homonuclear diatomic molecule is a molecule that consists of two atoms of the same element. Examples of homonuclear diatomic molecules are H₂ (hydrogen), Cl₂ (chlorine), and N₂ (nitrogen).

In these molecules, several types of molecular orbitals occur. The bonding in a homonuclear diatomic molecule is described using molecular orbitals. The molecular orbitals are filled according to the Pauli principle and Hund's rule, where each orbital can accommodate a maximum of two electrons with opposite spins. This approach helps us predict the stability of the molecule.

For diatomic molecules, there is only one bond, and the bond dipole moment determines the molecular polarity. Homonuclear diatomic molecules, such as Br₂ and N₂, have no difference in electronegativity, so their dipole moment is zero.

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