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What will OCCASIONALLY show up at 9-10 ppm on H NMR?

User Albaregar
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Final answer:

In 1H-NMR spectroscopy, chemical shifts at 9-10 ppm occasionally correspond to aldehyde protons. These are deshielded due to the adjacent oxygen atom in the carbonyl group. Aromatic protons can also appear downfield, but aldehyde signals are a common feature in this chemical shift range.

Step-by-step explanation:

In 1H-NMR spectroscopy, a chemical shift range of 9-10 ppm is typically indicative of aldehyde protons. These protons are deshielded due to the electronegative oxygen atom which is attached to the carbonyl group in aldehydes. Additionally, aromatic protons can also resonate downfield, and sometimes aromatic protons attached to electron-withdrawing groups can show up in this range. However, aldehyde protons are more consistently found at 9-10 ppm. The broad 'mountain' centered at about 3400 cm¹ described in the information relates to O-H stretching of alcohols in infrared spectroscopy, not 1H-NMR.

In the provided experimental notes, aromatic proton shifts are mentioned as well, which show significantly different chemical shifts and are not typically observed around 9-10 ppm unless particular substituents are present that drastically influence the electron density. Thus, when operating on an NMR spectrometer, as mentioned in the details using a Bruker Avance system, and when referencing to common deuterated solvents like CDCI3 or DMSO, one can expect aldehyde protons to show occasionally at the 9-10 ppm range. This is a key piece of information for interpreting these spectra.

User Etov
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