Final answer:
The line that will cause a compiler error is line 7, where an attempt is made to assign a new value to a constant variable.
Step-by-step explanation:
The line in the given program that will cause a compiler error is line 7. The error occurs because the variable MY_VAL is declared as a constant (const) on line 6, but on line 7, an attempt is made to assign a new value to it, which is not allowed for const variables.