Final answer:
Acetylene cannot be safely used at pressures greater than 103 Kpa (15 psi) due to the risk of explosive decomposition with sudden ignition.
Step-by-step explanation:
The question asks at what pressures acetylene cannot be used safely. Acetylene is a highly flammable and potentially unstable gas at high pressures; therefore, it cannot be safely used at pressures greater than 103 Kpa (15 psi). This is because at higher pressures, the gas can decompose explosively if there's a sudden ignition. For safety reasons, acetylene should always be handled with care and used within recommended limits.