83.3k views
5 votes
How is the partition coefficient defined?

a) Ratio of concentrations of solute in two immiscible solvents
b) Measure of solute temperature dependence
c) Ratio of solute concentrations at equilibrium
d) Measure of solute's molecular weight

User Darwyn
by
7.3k points

1 Answer

7 votes

Final answer:

The partition coefficient is the ratio of a solute's concentrations in two immiscible solvents at equilibrium, signifying the compound's distribution between the phases. It is critical for understanding and predicting the outcome of extraction and separation processes. Concentration measurements, such as molarity or molality, are essential in calculating this coefficient.

Step-by-step explanation:

The partition coefficient is defined as the ratio of concentrations of a solute in two immiscible solvents at equilibrium. This concept relates to the distribution of a single species between two phases that do not mix, like oil and water. The partition coefficient is a key parameter in processes such as extraction and separation. It indicates how a compound will distribute itself between two immiscible phases when they are in contact. If one phase is a gas and the other a liquid, the concept is akin to the Henry's law constant. When dealing with solid solutions or solid-liquid partitions, the solute's concentration in each phase is considered under the terms of equilibrium solubility.

Concentration is a quantitative measure informing us of the amount of solute present per volume of solvent, typically expressed in units like molarity or molality. In relation to partition coefficients, concentration helps in determining how much of the solute is in each phase. The higher the partition coefficient, the more likely the solute is to be found in the second phase compared to the first.

User Pavan Jadda
by
7.6k points