Final answer:
PbCl₂ has a larger solubility in water than CaF₂.
Step-by-step explanation:
In order to determine which compound has a larger solubility in water, we need to compare their solubility product constants (Ksp). The Ksp values for CaF₂ and PbCl₂ are 3.9 x 10⁻¹¹ and 1.7 x 10⁻⁵, respectively. The compound with the larger Ksp value will have a greater solubility in water. Therefore, PbCl₂ has a larger solubility in water than CaF₂.