Final answer:
To calculate the corrected volume of hydrogen gas at STP, we can use the combined gas law equation. Given the initial volume, temperature, atmospheric pressure, and vapor pressure of water, we can substitute the values into the equation to find the corrected volume.
Step-by-step explanation:
To calculate the corrected volume of hydrogen gas at STP, we can use the combined gas law equation. The equation is as follows:
V₂ = (V₁ x P₂ x T₁) / (P₁ x T₂)
Given the following values:
V₁ = 82.0 ml
P₁ = atmospheric pressure - vapor pressure of water = 762 mmHg - 18 mmHg = 744 mmHg
T₁ = -23°C + 273.15 = 250.15 K
P₂ = 760 mmHg
T₂ = 273.15 K
Substituting these values into the equation, we get:
V₂ = (82.0 ml x 760 mmHg x 250.15 K) / (744 mmHg x 273.15 K) = 64.0 ml
Therefore, the corrected volume of H2 gas at STP is 64.0 ml. Answer choice (b) is correct.