Final answer:
In combining the given intermediate chemical equations, PCl3(l) is the substance that cancels out as it is a product in the first equation and a reactant in the second.
Step-by-step explanation:
When combining the intermediate chemical equations, you cancel out the substance that appears on both sides of the equations. We have the first equation 2P(s) + 3Cl2(g) → 2PCl3(l) and the second equation PCl3(l) + Cl2(g) → PCl5(s). When these are combined, PCl3(l) appears as a product in the first equation and as a reactant in the second equation. Therefore, it cancels out.