Final answer:
To write the empirical formula from the percent composition of a compound, assume a 100 g sample, convert grams to moles, divide the moles by the smallest number obtained, and express as a ratio of whole numbers.
Step-by-step explanation:
To determine the empirical formula of a compound with a given percent composition, follow these steps:
- Assume a 100 g sample of the compound, which turns percentages into grams directly.
- Convert the mass of each element in grams to moles using the atomic mass of each element (from the periodic table).
- Divide all the moles by the smallest number of moles calculated.
- Round to the nearest whole number to get the ratio of the atoms in the compound.
For example, to find the empirical formula of a compound with 62.1% carbon, 10.5% hydrogen, and 27.4% oxygen:
- Take 62.1 g of carbon, 10.5 g of hydrogen, and 27.4 g of oxygen.
- Calculate the moles of each element: C (62.1 g / 12.01 g/mol), H (10.5 g / 1.008 g/mol), and O (27.4 g / 16.00 g/mol).
- Divide by the smallest number of moles to find the simplest whole number ratio.
- The result is the empirical formula for the compound, which could be written after determining the specific ratios.
This process yields the empirical formula based on the given elemental percentages.