Final answer:
The Development Team members should estimate the volume of work for each backlog item in Scrum.
Step-by-step explanation:
The volume of work estimation for each backlog item in Scrum should be done by the Development Team members. They are responsible for understanding the scope and requirements of each item and have the expertise to estimate the effort required to complete it. The Product Owner can provide guidance and insights, but it is the Development Team who ultimately determines the volume of work.