Final answer:
In Na₂O, the oxidation number for sodium is +1, while for oxygen it is -2, corresponding with the sodium cation and oxygen anion in the compound.
Step-by-step explanation:
The oxidation numbers of sodium (Na) and oxygen (O) atoms in Na₂O are +1 and -2, respectively. For ionic compounds such as Na₂O, it is standard to assign oxidation numbers separately for cations and anions. Sodium, being the cation, follows the guideline that its oxidation number is +1, as is typical for sodium in compounds.
Oxygen, generally, has an oxidation number of -2 except in peroxides where it is -1. Given that Na₂O is not a peroxide, each oxygen atom would have an oxidation number of -2.