Final answer:
The oxidizing agent in the reaction Fe(s) + Ni²⁺ (aq) → Fe²⁺(aq) + Ni(s) is Ni²⁺ because it gains electrons and is reduced (Option 4).
Step-by-step explanation:
The question asks which substance is the oxidizing agent in the reaction Fe(s) + Ni²⁺ (aq) → Fe²⁺(aq) + Ni(s). To determine the oxidizing agent, we must look at which substance is reduced. The substance that is reduced gains electrons during the reaction. In this case, nickel (Ni²⁺) gains two electrons to become nickel metal (Ni), thus it is reduced.
The substance that causes another to be reduced (and is itself oxidized) is the reducing agent, which is iron (Fe). Therefore, the reducing agent Fe is oxidized.
Since nickel was reduced, Ni²⁺ is the oxidizing agent, making choice 4) Ni²⁺ the correct answer.