Final answer:
Triacylglycerols are more efficient for energy storage than polysaccharides due to a higher hydrogen to oxygen ratio, leading to more energy release upon oxidation and their nonpolar nature, which doesn't bind water, making energy storage more concentrated.
Step-by-step explanation:
Triacylglycerols are considered more efficient stores of metabolic energy compared to polysaccharides primarily because of their higher hydrogen to oxygen ratio (answer a), which leads to greater energy release upon oxidation.
Unlike polysaccharides such as glycogen that are hydrophilic and bind to water, triacylglycerols are nearly nonpolar molecules and thus store energy in a more concentrated form without the additional weight of water.
This efficiency comes from the fact that fats and oils are in a more reduced form than glycogen (higher energy per mass) and release more energy per mass upon oxidation.