Final answer:
Metals and ionic compounds generally form crystalline solids, while substances consisting of large molecules or restricted movement molecules often form amorphous solids. Some substances can exist in both crystalline and amorphous forms.
Step-by-step explanation:
Metals and ionic compounds typically form ordered, crystalline solids. Substances that consist of large molecules, or a mixture of molecules whose movements are more restricted, often form amorphous solids. For example, candle waxes are amorphous solids composed of large hydrocarbon molecules. Some substances, such as silicon dioxide, can form either crystalline or amorphous solids, depending on the conditions under which it is produced. Also, amorphous solids may undergo a transition to the crystalline state under appropriate conditions.