Final answer:
The founder and first president of the National Council of Colored Women was Mary Church Terrell, who was also the first president of the National Association of Colored Women's Clubs.
Step-by-step explanation:
The founder and first president of the National Council of Colored Women was Mary Church Terrell. She was an activist, educator, writer, and leader who played a key role in the fight for civil rights and women's suffrage. Terrell was also the first president of the National Association of Colored Women's Clubs (NACWC), which was formed in 1896 as a national organization to promote and coordinate the activities of local African American women's organizations throughout the nation.