Final answer:
Under extreme conditions not found in nature, the radius of a localized s-orbital can reduce from its unpressurized solid state due to compression and repulsion between electrons.
Step-by-step explanation:
Under extreme conditions not found in nature, such as low temperature and high pressure, the radius of a localized s-orbital can reduce from its unpressurized solid state. When a solid is subjected to extreme pressure, the electrons in the s-orbitals are squeezed closer together, resulting in a decrease in radius. This decrease in radius is due to the compression of the electron cloud and the repulsion between electrons.