Final answer:
Magnetic dipoles in a magnetic field do not always align due to angular momentum and Larmor precession. The type of material affects the dipoles' behavior, and quantization applies to both the direction and magnitude of dipoles' magnetic moments.
Step-by-step explanation:
The behavior of magnetic dipoles in a magnetic field is an interesting phenomenon in physics. When a dipole is placed in a magnetic field, we might expect it to align with the field just like a compass needle does. However, this expected behavior doesn't always occur due to other factors at play.
In the scenario you've mentioned where dipoles enter a field at an angle, the reason they don't always align with the magnetic field to achieve maximum deflection is due to factors like angular momentum and Larmor precession. These phenomena resist the turning force exerted on the dipole by the magnetic field. Moreover, the rapid movement of the dipoles might prevent full alignment before they exit the field. The alignment of dipoles in a material also depends on the type of material, as ferromagnetic materials can become permanently magnetized, while paramagnetic materials will only show magnetization in the presence of an external magnetic field.
The quantization observed in dipoles in an external magnetic field doesn't relate just to the direction of their alignment but also to the magnitude of their quantized angular momentum and the magnetic dipole moment this momentum produces. So, while a dipole's orientation does affect the magnetic dipole moment, the magnitude of this moment is also quantized.