Final answer:
The equilibrium concentrations of Zn²⁺ and OH⁻ in a 0.0465-M solution of Zn(OH)₄²⁻ are [Zn²⁺] = 2.04 × 10⁻⁹ M and [OH⁻] = 2.04 × 10⁻⁹ M.
Step-by-step explanation:
To calculate the equilibrium concentrations of Zn²⁺ and OH⁻ in a 0.0465-M solution of Zn(OH)₄²⁻, we can use the dissociation constant (Kd).
The dissociation constant is given as Kd = 3.4 × 10⁻¹⁵. The equation for the dissociation of Zn(OH)₄²⁻ in water is Zn(OH)₄²⁻ ⇌ Zn²⁺ + 4OH⁻.
Since Zn(OH)₄²⁻ dissociates into one Zn²⁺ ion and four OH⁻ ions, the equilibrium concentrations would be [Zn²⁺] = 2.04 × 10⁻⁹ M and [OH⁻] = 2.04 × 10⁻⁹ M.