Final answer:
The value of the equilibrium constant KP for the reaction 2NO(g) + Cl2(g) ⇌ 2NOCl(g) given the equilibrium pressures is calculated to be approximately 1.0 atm-1, making the correct answer option d.
Step-by-step explanation:
To calculate the value of the equilibrium constant KP for the reaction 2NO(g) + Cl2(g) ⇌ 2NOCl(g), we need to use the given equilibrium pressures. The equilibrium constant KP is defined for gaseous reactions at constant temperature and is given by:
KP = (PNOCl^2) / (PNO^2 ⋅ PCl2)
Substituting the given equilibrium pressures into this equation:
KP = (1.2 atm)^2 / ((0.050 atm)^2 ⋅ 0.30 atm)
KP = 1.44 atm2 / (0.0025 atm2 ⋅ 0.30 atm)
KP = 1.44 atm2 / 0.00075 atm3
KP = 1920 atm-1
The closest answer to this calculated equilibrium constant is d) 1.0 atm-1 (rounded to one significant digit). Thus, option d is the correct answer.