Final answer:
Silicon does not form an allotrope with a graphite structure due to its tendency to form sp³ hybridized tetrahedral structures, unlike carbon which can have sp² hybridized atoms in graphite, allowing for the formation of stable double bonds and planar arrangements.
Step-by-step explanation:
The reason there is no allotrope of silicon with a graphite structure is because of the differences in the chemical behavior of silicon compared to carbon.
Since silicon atoms do not tend to form double bonds and have a tetrahedral geometry due to their sp³ hybridization, they cannot arrange in hexagonal planes like carbon atoms in graphite.
This is contrasted with carbon's ability to form stable double bonds due to its sp² hybridized carbon atoms in graphite's planar structure.