Final answer:
The overall reaction in the electrolysis of molten lithium chloride is 2LiCl → 2Li + Cl2. Correct option is a.
Step-by-step explanation:
In the electrolysis of molten lithium chloride, the overall reaction can be represented by the balanced equation:
2LiCl → 2Li + Cl2
This equation shows that 2 moles of lithium chloride produce 2 moles of lithium and 1 mole of chlorine gas.