Final answer:
Phosphorous acid forms only two series of salts because the third hydrogen atom is weakly acidic and does not participate in salt formation.
Step-by-step explanation:
Phosphorous acid, H3PO3, forms only two series of salts because the third hydrogen atom is weakly acidic and does not participate in salt formation. The molecule contains three hydrogen atoms, but only the two hydrogen atoms bonded to an oxygen atom are acidic. The bond between phosphorus and the third hydrogen atom is not very acidic and does not easily ionize to form salts.