Final answer:
b) ml = 0, ±1, ±2, ±3, ±4
The possible values of m_l for an electron in the n=4 state are m_l = 0, ±1, ±2, ±3, ±4, spanning across all possible angular momentum quantum numbers (l) from 0 to 3.
Step-by-step explanation:
The possible values of ml for an electron in the n=4 state can be determined on the basis of the quantum number l (the angular momentum quantum number).
For any given value of n, the possible values of l range from 0 to n-1. This means when n is 4, l can be 0, 1, 2, or 3. The magnetic quantum number, ml, depends on the value of l, and it can take on values from -l to +l, including 0.
Thus, given n=4 and consequently l=3, the values of ml would include -3, -2, -1, 0, +1, +2, and +3.
When considering values of ml for all allowable values of l, the complete set for an electron in the n=4 state would be ml = 0, ±1, ±2, ±3, ±4, since these include all possible ml for l=0 to l=3.