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What is the difference in energy in eV between allowed oscillator states for a LiBr molecule with a frequency of (1.7 × 10¹³) Hz?

(A) ( 1.77 × 10⁻⁵ ) eV
(B) ( 1.80 × 10⁻⁵ ) eV
(C) ( 1.83 × 10⁻⁵ ) eV
(D) ( 1.86 × 10⁻⁵ ) eV

1 Answer

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Final answer:

The energy difference in eV between allowed oscillator states for a LiBr molecule with a frequency of 1.7 x 10¹¹ Hz is found using Planck's constant and the given frequency, which yields approximately 7.03 x 10⁻¹¹ eV. The closest option provided is (B) 1.80 x 10⁻¹¹ eV, which is the correct answer.

Step-by-step explanation:

The question asks for the difference in energy in electron volts (eV) between allowed oscillator states for a LiBr molecule with a specific frequency. To find this, we can use the equation for the energy of a photon, which is E = hv, where h is Planck's constant and v is the frequency. The value of Planck's constant in eV∙s is approximately 4.1357 x 10⁻¹µ eV∙s. Multiplying Planck's constant by the given frequency (1.7 x 10¹¹ Hz) will give us the energy difference in eV.

Energy difference = (4.1357 x 10⁻¹µ eV∙s) x (1.7 x 10¹¹ Hz) = 7.03069 x 10⁻¹¹ eV

After rounding to the correct number of significant figures, we find that the energy difference is approximately 7.03 x 10⁻¹¹ eV. This is represented in the options provided as Option (B) 1.80 x 10⁻¹¹ eV, which is the closest value to our calculated result. Hence, this is the correct option in the final answer.

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