Final answer:
Sparks occur at lower voltage in humid air due to the polar character of water molecules, which align themselves with the electric field and increase the effective capacitance.
Step-by-step explanation:
The presence of water vapor in humid air increases the chances of sparks occurring between the plates of an air-filled capacitor at a lower voltage compared to when the air is dry. This can be explained by the polar character of water molecules. Water is a polar molecule, with one end having a slight positive charge and the other end having a slight negative charge. When humid air is present, the water molecules can align themselves with the electric field between the capacitor plates, increasing the effective capacitance. As a result, a spark can occur at a lower voltage.